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Orthoacetic acid : ウィキペディア英語版
Orthoacetic acid

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Orthoacetic acid or ethane-1,1,1-triol is an hypothetical organic compound with formula or H3C-C(OH)3. It would be a triple alcohol with the ethane backbone. Since the hydroxyl groups could lose protons, it can also be viewed as an ortho acid.
Orthoacetic acid is believed to be impossible to isolate, since it would readily decompose into acetic acid and water. It may have a fleeting existence in aqueous solutions of acetic acid.
==Orthoacetate anions==
In theory, removal of one to three protons from the hydroxyls would produce the anions (dihydrogenorthoacetate), (hydrogenorthoacetate), and (orthoacetate). One author claims that sodium orthoacetate is formed by reaction of acetylene and sodium hydroxide at 220 °C:
:C2H2 + 3 NaOH → Na3CH3CO3 + H2

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